Описание: This handbook is intended as a single comprehensive reference ranging from the controlled ring-opening polymerization methods to the polymer materials of industrial interest. Chapters written by internationally acclaimed experts in their respective fields cover both basic principles and up-to-date information. All main classes of monomers including heterocyclics, cyclic olefins and alkynes, and cycloalkanes, are discussed separately as well as their specificities regarding the ring-opening polymerization techniques, the mechanisms, the degree of control, the properties of the related polymers and their applications. The two last chapters are devoted to the implementation of green chemistry in ring-opening polymerization processes.
Автор: Graeme Moad Название: The Chemistry of Radical Polymerization, ISBN: 0080442862 ISBN-13(EAN): 9780080442860 Издательство: Elsevier Science Рейтинг: Цена: 9504 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: Aims to provide a framework for understanding free radical polymerization and create a definable link between synthesis conditions and polymer structure and properties. This book contains a chapter on the growing field of living radical polymerization.
Описание: The purpose of this textbook is to teach senior or graduate-level students and practitioners how to quantitatively model step-growth polymerization plants and predict the properties of the product polymer. The book attempts to capture the quantitative relationships between key process input variables (KPIVs) and key process output variables (KPOVs), and focuses on the integrated modeling of an entire polymer manufacturing train (including reactors, separators, recycle coolers/condensers, etc.), not merely reactors alone. To model such a wide range of unit operations, the book integrates all of our fundamental models of physical and thermodynamic properties, phase equilibrium, polymerization kinetics, heat- and mass-transfer limitations, together with predictive or empirical models of polymer end-use properties and computer-aided design tools. After studying the text and working through the design examples, the reader should be able to quantitatively model their plants using either a custom simulation written entirely by the model developer or Aspen Technologys commercial simulation packages, Polymers Plus and Aspen Custom Modeler. To enhance the presentation of this very diverse subject, the author's organized the book into three parts. Part I teaches the fundamentals of step-growth polymer process modeling and product design. To illustrate these fundamentals, the book provides many design problems and solutions. These solutions employ a modular, open-source FORTRAN code that the author's develop. Part II re-emphasizes key aspects of step-growth polymerization process and product design using Polymers Plus. Part III introduces some advanced topics in polymerization process modeling, such as fine-tuning model parameters to fit process data, multiscale modeling of step-growth polymerization processes, and recent achievements and future challenges of polymer process modeling.
Автор: Jordan Название: Surface-Initiated Polymerization I ISBN: 3540302476 ISBN-13(EAN): 9783540302476 Издательство: Springer Рейтинг: Цена: 27066 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Автор: Buchmeiser Название: Metathesis Polymerization ISBN: 354023358X ISBN-13(EAN): 9783540233589 Издательство: Springer Рейтинг: Цена: 24976 р. Наличие на складе: Есть у поставщика Поставка под заказ.
This book is the first of a series providing a comprehensive resource on cationic polymerization. All three volumes are written in a manner that is easy to comprehend, even by undergraduate college students, and are designed to help the reader decipher an otherwise complex subject. Topics for each volume are presented in an order that build successively on material presented in prior books. The series is comprehensive, so even those who are well-versed in the discipline will find invaluable information in each volume. Through study of these books, the reader can become an expert in this subset of polymer science without ever having attended courses on the subject.
This first volume focuses on the most commercially-relevant technique: non-living polymerization of olefins. It provides a complete overview of methods (including those used industrially) that have been devised to effect such polymerizations, dating from the very inception of the technique through the present. From this, chemists can make educated choices on how to best design a polymerization system meeting their specific requirements. Mechanistic aspects of the chemistry are presented throughout the text with ample chemical drawings, and this information can help the reader develop new polymerization systems. This work also emphasizes improvements (many being reported for the first time) made to the green aspects of the cationic methodology, a facet of growing importance for today's chemist. This is the only book on cationic polymerization that contains a section dedicated to experimental techniques. The reader can use the information contained within both to safely conduct their own bench-top to pilot plant scale experimentation.
The other volumes in the 3-part set are: Vol 2: Thermodynamics/Kinetics/Spectral Properties; Vol 3: Living Polymerizations.
Автор: George Odian Название: Principles of Polymerization, 4th Edition ISBN: 0471274003 ISBN-13(EAN): 9780471274001 Издательство: Wiley Рейтинг: Цена: 14091 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: This is the new edition of a classic text and reference. The large chains of molecules known as polymers are currently used in everything from "wash and wear" clothing to rubber tires to protective enamels and paints. Yet the practical applications of polymers are only increasing; innovations in polymer chemistry constantly bring both improved and entirely new uses for polymers onto the technological playing field. "Principles of Polymerization, Fourth Edition" presents the classic text on polymer synthesis, fully updated to reflect today's state of the art. New and expanded coverage in the Fourth Edition includes: Metallocene and post-metallocene polymerization catalysts; living polymerizations (radical, cationic, anionic); Dendrimer, hyperbranched, brush, and other polymer architectures and assemblies; Graft and block copolymers; High-temperature polymers; Inorganic and organometallic polymers; Conducting polymers; Ring-opening polymer ization; In vivo and in vitro polymerization. Appropriate for both novice and advanced students as well as professionals, this comprehensive yet accessible resource enables the reader to achieve an advanced, up-to-date understanding of polymer synthesis. Different methods of polymerization, reaction parameters for synthesis, molecular weight, branching and crosslinking, and the chemical and physical structure of polymers all receive ample coverage. There is a thorough discussion at the elementary level prefaces each topic, with a more advanced treatment following. Yet the language throughout remains straightforward and geared towards the student. Extensively updated, "Principles of Polymerization, Fourth Edition" provides an excellent textbook for today's students of polymer chemistry, chemical engineering, and materials science, as well as a current reference for the researcher or other practitioner working in these areas.
Описание: The book highlights the latest developments of new catalysts for stereoselective metathesis and catalysts with considerable functional group tolerance which have permitted the synthesis of novel materials. It also shows that these new catalysts in addition to Ring Opening Metathesis Polymerisation (ROMP), Acyclic Diene Metathesis (ADMET), and Cross metathesis (CM) are now powerful tools for Ring Closing Metathesis (RCM) which has found many applications in the synthesis of natural products.
Описание: This original research, published here for the first time in book format, describes in detail an entirely new process for preparing emulsions and alkyd resin emulsions, leading to many applications, foremost among them the formulation of new paints. This research has also spawned the international field of alkyd and alkyd-hybrid miniemulsions. Pioneering technology is presented for the emulsification of alkyd resins and vegetable oils used in coatings, adhesives, and inks applications. Essential technical information is provided for researchers and manufacturers involved in the emulsification of resins, oils, and pigments. Emulsification and Polymerization in Alkyd Resins is an indispensable reference book for every type of coatings and resins manufacturer or research group.
Описание: The World Polymer Congresses are highlights in the calendars of polymer scientists. In July 2000, the 38th International Symposium on Macromolecules (sponsored by IUPAC) was held in Warsaw, attended by00 participants from 54 countries. The program covered all areas of macromolecular chemistry---from various kinds of polymer synthesis to theory and modeling of polymer systems; from polymer properties and characterization to industrial processing. All types of polymers (e.g., crystalline, branched, blends, composites and biorelated) were discussed, and industrial and educational perspectives were explored. Volumes 174 and 175 of Macromolecular Symposia present almost all the Invited and Plenary Lectures from the Congress and represent an excellent overview of the current state of macromolecular science.
Описание: Even some fifty years after their discovery, transition metals have lost none of their fascination. The use of complex compounds in these elements has not only revolutionized synthesis in the laboratory, bhas also led to them playing an important role in many industrial applications. Each year, millions of tons of plastics are produced around the world and, by varying the ligands in the catalytically active compounds, the properties of the resulting polymers can even be tailored for use. For this purpose, sandwich compounds from early transition metals have been common until now, but interest has focused increasingly on the late transition metals. In this book, the world's leading authors from research and industry discuss the latest developments in research into palladium, zinc, iron and nickel catalysis. In so doing, they systematically introduce readers to the basic principles and illustrate how these innovative catalysts can be effectively used for polymerizations. The result is an ideal reference work, invaluable for every organic chemist working in catalysis or polymer research.
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