This book is the first of a series providing a comprehensive resource on cationic polymerization. All three volumes are written in a manner that is easy to comprehend, even by undergraduate college students, and are designed to help the reader decipher an otherwise complex subject. Topics for each volume are presented in an order that build successively on material presented in prior books. The series is comprehensive, so even those who are well-versed in the discipline will find invaluable information in each volume. Through study of these books, the reader can become an expert in this subset of polymer science without ever having attended courses on the subject.
This first volume focuses on the most commercially-relevant technique: non-living polymerization of olefins. It provides a complete overview of methods (including those used industrially) that have been devised to effect such polymerizations, dating from the very inception of the technique through the present. From this, chemists can make educated choices on how to best design a polymerization system meeting their specific requirements. Mechanistic aspects of the chemistry are presented throughout the text with ample chemical drawings, and this information can help the reader develop new polymerization systems. This work also emphasizes improvements (many being reported for the first time) made to the green aspects of the cationic methodology, a facet of growing importance for today's chemist. This is the only book on cationic polymerization that contains a section dedicated to experimental techniques. The reader can use the information contained within both to safely conduct their own bench-top to pilot plant scale experimentation.
The other volumes in the 3-part set are: Vol 2: Thermodynamics/Kinetics/Spectral Properties; Vol 3: Living Polymerizations.
Описание: The emulsion polymerization process has several distinct advantages over other methods when it comes to the production of many of the polymers used in commercial and industrial products. Firstly, the physical state of the emulsion (colloidal) system is easier to control than most (it has less problems related to changes in temperature and viscosity); further, it differs from other methods of polymerization in that the polymer molecular weight can be increased greatly without decreasing the polymerization rate. And the fact that emulsion polymers are created (and often sold) in water means there are fewer toxicity and safety concerns than exist for their solvent-based counterparts. This book provides a comprehensive, up-to-date reference on emulsion polymerization methods, focusing on the fundamental mechanisms and kinetics of each process as well as how they can be applied to the manufacture of environmentally-friendly polymeric materials. Topics covered include: conventional emulsion polymerization miniemulsion polymerization microemulsion polymerization industrial emulsion polymerization processes (primarily the semibatch and continuous reactions systems) important end-use properties of emulsion polymer (latex) products industrial applications in paints, coatings, adhesives, paper & board, etc.
Автор: Korolyov, Gennady V. Mogilevich, Michael Название: Three-dimensional free-radical polymerization ISBN: 3540875662 ISBN-13(EAN): 9783540875666 Издательство: Springer Рейтинг: Цена: 20895 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: Discusses the developments in the field of three-dimensional free-radical polymerization, as well as the achievements, problems, methods used in the field and modern development trends. This book connects the basics of the synthesis of cross-linked and hyper-branched polymers with their physico-mechanical properties.
Описание: Covers the IUPAC-sponsored International Symposium on `Radical Polymerization: Kinetics and Mechanism` held in Il Ciocco (Italia) during the week September 3-8, 2006. This book also covers various aspects from fundamentals to polymer reaction engineering. It is suitable for chemists in industry and academia.
Автор: Barner-Kowollik Название: Handbook of RAFT Polymerization ISBN: 3527319247 ISBN-13(EAN): 9783527319244 Издательство: Wiley Рейтинг: Цена: 21945 р. Наличие на складе: Поставка под заказ.
Описание: The Handbook of RAFT Polymerization assembles up-to-date knowledge about the RAFT process, ranging from its mechanistic underpinnings to practical applications, providing high value for researchers and research managers seeking up-to-date information about the RAFT process, its scope and limitations.
Автор: Matyjaszewski, Krzysztof Название: Controlled/Living Radical Polymerization ISBN: 0841239916 ISBN-13(EAN): 9780841239913 Издательство: Oxford Academ Рейтинг: Цена: 11274 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: This book is addressed to chemists who are interested in radical processes; especially in controlled/living radical polymerization. It focuses on mechanisms of the involved reactions, synthesis of new functional materials and discloses new applications. The book illustrates the most recent accomplishments in the field presented at the ACS Fall 2005 Meeting in Washington, DC.
Описание: This handbook is intended as a single comprehensive reference ranging from the controlled ring-opening polymerization methods to the polymer materials of industrial interest. Chapters written by internationally acclaimed experts in their respective fields cover both basic principles and up-to-date information. All main classes of monomers including heterocyclics, cyclic olefins and alkynes, and cycloalkanes, are discussed separately as well as their specificities regarding the ring-opening polymerization techniques, the mechanisms, the degree of control, the properties of the related polymers and their applications. The two last chapters are devoted to the implementation of green chemistry in ring-opening polymerization processes.
Описание: The book will comprehensively chart the development and current state of the art within the field of immobilized single-site olefin polymerization catalysts. Providing a clear rationale for the goals and ultimately the mark of success of an immobilization procedure. In addition, the book will put these catalytic systems into context by containing sections on the latest developments in competing and complementary technologies, such as traditional heterogeneous catalysts, particle growth and process technology.
Автор: Graeme Moad Название: The Chemistry of Radical Polymerization, ISBN: 0080442862 ISBN-13(EAN): 9780080442860 Издательство: Elsevier Science Рейтинг: Цена: 9504 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: Aims to provide a framework for understanding free radical polymerization and create a definable link between synthesis conditions and polymer structure and properties. This book contains a chapter on the growing field of living radical polymerization.
Описание: The World Polymer Congresses are highlights in the calendars of polymer scientists. In July 2000, the 38th International Symposium on Macromolecules (sponsored by IUPAC) was held in Warsaw, attended by00 participants from 54 countries. The program covered all areas of macromolecular chemistry---from various kinds of polymer synthesis to theory and modeling of polymer systems; from polymer properties and characterization to industrial processing. All types of polymers (e.g., crystalline, branched, blends, composites and biorelated) were discussed, and industrial and educational perspectives were explored. Volumes 174 and 175 of Macromolecular Symposia present almost all the Invited and Plenary Lectures from the Congress and represent an excellent overview of the current state of macromolecular science.
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