Metal Catalyzed Cascade Reactions, Thomas J.J. M?ller
Автор: Xu Название: Catalytic Cascade Reactions ISBN: 1118016025 ISBN-13(EAN): 9781118016022 Издательство: Wiley Рейтинг: Цена: 22168.00 р. Наличие на складе: Поставка под заказ.
Описание: The development of catalytic versions of cascade reactions has become one of the most active and burgeoning reaction areas in organic synthesis.
Описание: The series Topics in Heterocyclic Chemistry presents critical reviews on present and future trends in the research of heterocyclic compounds. Overall the scope is to cover topics dealing with all areas within heterocyclic chemistry, both experimental and theoretical, of interest to the general heterocyclic chemistry community. The series consists of topic related volumes edited by renowned editors with contributions of experts in the field.
Автор: Yusuke Ohta Название: Copper-Catalyzed Multi-Component Reactions ISBN: 3642267017 ISBN-13(EAN): 9783642267017 Издательство: Springer Рейтинг: Цена: 15372.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: As the concept of Green Chemistry becomes ever more important, the findings presented in this book may provide efficient and atom-economical approaches to the diversity-oriented synthesis of bioactive compounds containing a complex structure.
Автор: Soriano Название: Computational Mechanisms of Au and Pt Catalyzed Reactions ISBN: 3642210821 ISBN-13(EAN): 9783642210822 Издательство: Springer Рейтинг: Цена: 45712.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: Structure, Bonding, and Reactivity of Reactant Complexes and Key Intermediates, by Elena Soriano and Jos? Marco-Contelles.-Cycloisomerization of 1,n-Enynes Via Carbophilic Activation, by Patrick Yves Toullec and V?ronique Michelet.- DFT-Based Mechanistic Insights into Noble Metal-Catalyzed Rearrangement of Propargylic Derivatives: Chirality Transfer Processes, by Olalla Nieto Faza and Angel R. de Lera.-N-Heterocyclic Carbene Complexes of Au, Pd, and Pt as Effective Catalysts in Organic Synthesis, by Andrea Correa, Steven P. Nolan and Luigi Cavallo.-Activation of Allenes by Gold Complexes: A Theoretical Standpoint, by Max Malacria, Louis Fensterbank and Vincent Gandon.-Heterocyclization of Allenes Catalyzed by Late Transition Metals: Mechanisms and Regioselectivity, by Benito Alcaide, Pedro Almendros, Teresa Mart?nez del Campo, Elena Soriano and Jos? Marco-Contelles.-Gold-Catalyzed Cycloadditions Involving Allenes: Mechanistic Insights from Theoretical Studies, by Sergi Montserrat, Gregori Ujaque, Fernando L?pez, Jos? L. Mascare?as and Agust? Lled?s.-
Автор: Elena Soriano; Jos? Marco-Contelles Название: Computational Mechanisms of Au and Pt Catalyzed Reactions ISBN: 3642268854 ISBN-13(EAN): 9783642268854 Издательство: Springer Рейтинг: Цена: 43100.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание:
Structure, Bonding, and Reactivity of Reactant Complexes and Key Intermediates, by Elena Soriano and Jose Marco-Contelles.-
Cycloisomerization of 1, n-Enynes Via Carbophilic Activation, by Patrick Yves Toullec and Veronique Michelet.-
DFT-Based Mechanistic Insights into Noble Metal-Catalyzed Rearrangement of Propargylic Derivatives: Chirality Transfer Processes, by Olalla Nieto Faza and Angel R. de Lera.-
N-Heterocyclic Carbene Complexes of Au, Pd, and Pt as Effective Catalysts in Organic Synthesis, by Andrea Correa, Steven P. Nolan and Luigi Cavallo.-
Activation of Allenes by Gold Complexes: A Theoretical Standpoint, by Max Malacria, Louis Fensterbank and Vincent Gandon.-
Heterocyclization of Allenes Catalyzed by Late Transition Metals: Mechanisms and Regioselectivity, by Benito Alcaide, Pedro Almendros, Teresa Martinez del Campo, Elena Soriano and Jose Marco-Contelles.-
Gold-Catalyzed Cycloadditions Involving Allenes: Mechanistic Insights from Theoretical Studies, by Sergi Montserrat, Gregori Ujaque, Fernando Lopez, Jose L. Mascarenas and Agusti Lledos.-
Описание: This thesis presents the latest developments in new catalytic C–C bond formation methods using easily accessible carboxylate salts through catalytic decarboxylation with good atom economy, and employing the sustainable element iron as the catalyst to directly activate C–H bonds with high step efficiency. In this regard, it explores a mechanistic understanding of the newly discovered decarboxylative couplings and the catalytic reactivity of the iron catalyst with the help of density functional theory calculation. The thesis is divided into two parts, the first of which focuses on the development of a series of previously unexplored, inexpensive carboxylate salts as useful building blocks for the formation of various C–C bonds to access valuable chemicals. In turn, the second part is devoted to several new C–C bond formation methodologies using the most ubiquitous transition metal, iron, as a catalyst, and using the ubiquitous C–H bond as the coupling partner.
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