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Molecular Rearrangements in Organic Synthesis, Rojas, Christian M.



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Автор: Rojas, Christian M.
Название:  Molecular Rearrangements in Organic Synthesis   (Кристиан Рохас: Перестановка молекул в органическом синтезе)
Издательство: Wiley
Классификация:
ISBN: 111834796X
ISBN-13(EAN): 9781118347966
Обложка/Формат: Hardback
Страницы: 776
Вес: 1.19 кг.
Дата издания: 04.12.2015
Серия: Chemistry
Язык: English
Иллюстрации: Illustrations
Размер: 239 x 168 x 45
Читательская аудитория: Professional & vocational
Ключевые слова: Chemistry
Ссылка на Издательство: Link
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Поставляется из: Англии
Описание: Designed for practitioners of organic synthesis, this book helps chemists understand and take advantage of rearrangement reactions to enhance the synthesis of useful chemical compounds. The book discusses synthetic applications for natural products, medicinal compounds, functional materials, and physical organic chemistry.



Mean oscillations and equimeasurable rearrangements of functions

Автор: Korenovskii, Anatolii
Название: Mean oscillations and equimeasurable rearrangements of functions
ISBN: 3540747087 ISBN-13(EAN): 9783540747086
Издательство: Springer
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Цена: 3652 р.
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Описание: Considers various applications of equimeasurable function rearrangements to the "best constant"- type problems. This volume includes a product-space extension of the Rising Sun lemma, a product-space version of the John-Nirenberg inequality for bounded mean oscillation (BMO) functions with sharp exponent, and Gurov-Reshetnyak, reverse Holder.

Sulfur-Mediated Rearrangements II

Автор: Schaumann Ernst
Название: Sulfur-Mediated Rearrangements II
ISBN: 3540680993 ISBN-13(EAN): 9783540680994
Издательство: Springer
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Цена: 32228 р.
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Описание: With contributions by numerous experts

The Claisen Rearrangement: Methods and Applications

Автор: Martin Hiersemann
Название: The Claisen Rearrangement: Methods and Applications
ISBN: 3527308253 ISBN-13(EAN): 9783527308255
Издательство: Wiley
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Цена: 23100 р.
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Описание: The first comprehensive coverage of all facets of the Claisen rearrangementd its variants. As such, this book helps synthetic chemists to exploit the vast potential of this elegant C-C linking reaction, discusses a wealth of catalytic options, and gives those more theory-minded chemists a detailed insight into the mechanistic aspects of the Claisen rearrangement. An invaluable source of information and a ready reference for all organic and catalytic chemists, as well as those working with/on organometallics, and in industry.

Novel Selenium-Mediated Rearrangements and Cyclisations

Автор: Shahzad
Название: Novel Selenium-Mediated Rearrangements and Cyclisations
ISBN: 3642331726 ISBN-13(EAN): 9783642331725
Издательство: Springer
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Цена: 14629 р.
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Описание: This book investigates carbon nucleophiles in selenocyclisations, as well as reaction protocols for performing such reactions catalytically. Details electrophilic selenium-mediated reactions and strategies using selenium catalysts and more.

Sulfur-mediated rearrangements

Название: Sulfur-mediated rearrangements
ISBN: 3540680977 ISBN-13(EAN): 9783540680970
Издательство: Springer
Рейтинг:
Цена: 36471 р.
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Описание: In their analysis of experiments and in their planning of syntheses, organic chemistsconsciouslyorunconsciouslytendtousetheprincipleofleastmotion, thechemicalequivalentofOccam'srazor. Inrearrangementreactionsthispr- ciple is violated and may make rearrangements problematic reactions. At the sametime, thereisalwaysfascinationintheunexpectedandsorearrangement reactionsarealsoanattractive?eldofstudy. Consequently, ourunderstanding of rearrangement reactions is now quite advanced and allows strategic uses in organic synthesis. Here, a helpful tool that may easily be overlooked is thein?uence oforganosulfurfunctionalitiesontheserearrangements. Infact, the presence of sulfur may make rearrangements predictable and productive or allow speci?c transformations which would otherwise require a tedious synthetic detour. The present account is meant to spread this knowledge. In addition, an introductory chapter gives a survey of the basics of organosulfur chemistry to put the information in the individual chapters into perspective and to help readers who are less familiar with the peculiarities of sulfur in an organicenvironment. Theamountofmaterialrequiringcoveragewassovastthatthevolumehadto besplitintotwoparts. Wehopethatreaderswillappreciatethecomprehensive and up-to-date information on sulfur-mediated rearrangements. Fortunately, leading experts were available to write the individual chapters and provide state-of-the-artreviews ofthecurrent researchonsulfur-mediated rearran- ments. It was a pleasure to work with these colleagues and I appreciate their involvement in spite of many other obligations. This volume should help the chemical community in their synthetic workand so it was worththe effort. Clausthal-Zellerfeld, October 2006 Ernst Schaumann Contents SulfurisMoreThantheFatBrotherofOxygen. AnOverviewofOrganosulfurChemistry E. Schaumann. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 RecentAdvancesinPummererReactions S. Akai-Y. Kita . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35 1,2-SulfurMigrations A. W. Sromek-V. Gevorgyan. . . . . . . . . . . . . . . . . . . . . . . . 77 1,3-SulfurShifts: MechanismandSyntheticUtility S. K. Bur. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125 AuthorIndexVolumes251-274. . . . . . . . . . . . . . . . . . . . . . 173 Subject Index. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 183 ContentsofVolume275 Sulfur-MediatedRearrangementsII Volume Editor: Ernst Schaumann ISBN: 978-3-540-68099-4 2,3]-Sigmatropic RearrangementsofAllylic Sulfur Compounds M. Reggelin 2,3]Sigmatropic RearrangementsofPropargylic andAllenicSystems S. Braverman -M.

Combinatorics of genome rearrangements

Автор: Fertin, Guillaume, E
Название: Combinatorics of genome rearrangements
ISBN: 0262062828 ISBN-13(EAN): 9780262062824
Издательство: MIT Press
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Цена: 1731 р.
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Описание: A comprehensive survey of a rapidly expanding field of combinatorial optimization, mathematically oriented but offering biological explanations when required.

Sulfur-Mediated Rearrangements I

Автор: Ernst Schaumann; S. Akai; S.K. Bur; V. Gevorgyan;
Название: Sulfur-Mediated Rearrangements I
ISBN: 3642087779 ISBN-13(EAN): 9783642087776
Издательство: Springer
Рейтинг:
Цена: 36471 р.
Наличие на складе: Есть у поставщика Поставка под заказ.

Описание: In their analysis of experiments and in their planning of syntheses, organic chemistsconsciouslyorunconsciouslytendtousetheprincipleofleastmotion, thechemicalequivalentofOccam'srazor. Inrearrangementreactionsthispr- ciple is violated and may make rearrangements problematic reactions. At the sametime, thereisalwaysfascinationintheunexpectedandsorearrangement reactionsarealsoanattractive?eldofstudy. Consequently, ourunderstanding of rearrangement reactions is now quite advanced and allows strategic uses in organic synthesis. Here, a helpful tool that may easily be overlooked is thein?uence oforganosulfurfunctionalitiesontheserearrangements. Infact, the presence of sulfur may make rearrangements predictable and productive or allow speci?c transformations which would otherwise require a tedious synthetic detour. The present account is meant to spread this knowledge. In addition, an introductory chapter gives a survey of the basics of organosulfur chemistry to put the information in the individual chapters into perspective and to help readers who are less familiar with the peculiarities of sulfur in an organicenvironment. Theamountofmaterialrequiringcoveragewassovastthatthevolumehadto besplitintotwoparts. Wehopethatreaderswillappreciatethecomprehensive and up-to-date information on sulfur-mediated rearrangements. Fortunately, leading experts were available to write the individual chapters and provide state-of-the-artreviews ofthecurrent researchonsulfur-mediated rearran- ments. It was a pleasure to work with these colleagues and I appreciate their involvement in spite of many other obligations. This volume should help the chemical community in their synthetic workand so it was worththe effort. Clausthal-Zellerfeld, October 2006 Ernst Schaumann Contents SulfurisMoreThantheFatBrotherofOxygen. AnOverviewofOrganosulfurChemistry E. Schaumann. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 RecentAdvancesinPummererReactions S. Akai-Y. Kita . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35 1,2-SulfurMigrations A. W. Sromek-V. Gevorgyan. . . . . . . . . . . . . . . . . . . . . . . . 77 1,3-SulfurShifts: MechanismandSyntheticUtility S. K. Bur. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125 AuthorIndexVolumes251-274. . . . . . . . . . . . . . . . . . . . . . 173 Subject Index. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 183 ContentsofVolume275 Sulfur-MediatedRearrangementsII Volume Editor: Ernst Schaumann ISBN: 978-3-540-68099-4 2,3]-Sigmatropic RearrangementsofAllylic Sulfur Compounds M. Reggelin 2,3]Sigmatropic RearrangementsofPropargylic andAllenicSystems S. Braverman -M.

Glycoscience / Epimerisation, Isomerisation and Rearrangement Reactions of Carbohydrates

Автор: StГјtz Arnold E.
Название: Glycoscience / Epimerisation, Isomerisation and Rearrangement Reactions of Carbohydrates
ISBN: 3540413839 ISBN-13(EAN): 9783540413837
Издательство: Springer
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Цена: 44831 р.
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Описание: With contributions by numerous experts

Domino and Intramolecular Rearrangement Reactions as Advance

Автор: Witczak Zbigniew J
Название: Domino and Intramolecular Rearrangement Reactions as Advance
ISBN: 1119044200 ISBN-13(EAN): 9781119044208
Издательство: Wiley
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Цена: 15939 р.
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Описание: The book consists of a brief introduction, a foreward provided byprofessor Danishefsky of Columbia University, and about 14 -16 chapters, each written by one or two eminent scholars/authorsdescribing their recent research in the area of either dominoreactions or intramolecular rearrangements in carbohydratechemistry. Three or
four chapters will be reviews. The domino (cascade, tandem)reactions are always intramolecular. They are usually very fast, clean and offer highly complex structures in a one pot process.Intramolecular rearrangements offer very similar advantages andoften lead to highly complex products as well. Although manyrecently isolated carbohydrates fulfill various sophisticatedfunctions, their structures are often very complex. The editorscover the broadest scope of novel methodologies possible. All thesynthetic and application aspects of domino/cascade reactions areexplored in this book. A second theme that will be covered isintramolecular rearrangement, which is also fast, stereoselective, and often constitutes one or more steps of domino /cascade process.Selected examples of intramolecular rearrangements are presented.Together, both processes offer an elegant and
convenient approach to the synthesis of many complex molecules, which are normally difficult to synthesize via alternative routes.It appears that domino and intramolecular rearrangements areideally suited to synthesize certain specific modifiedmonosaccharides. What is particularly important is that bothprocesses are intermolecular and almost always yield products withvery well-defined stereochemistry. This high definition isabsolutely crucial when synthesizing advanced, modified mono andoligosaccharides. The choice of contributors reflects anemphasis
on both therapeutic and pharmacological aspects of carbohydratechemistry.

Organic Synthesis and Molecular Engineering

Автор: Nielsen
Название: Organic Synthesis and Molecular Engineering
ISBN: 1118150929 ISBN-13(EAN): 9781118150924
Издательство: Wiley
Рейтинг:
Цена: 14669 р.
Наличие на складе: Поставка под заказ.

Описание: With a focus on methods and practices for how to engineer functionality into organic molecules, Organic Synthesis and Molecular Engineering takes a synthesis-oriented approach to organic materials chemistry.

Organic Conductors, Superconductors and Magnets: From Synthesis to Molecular Electronics

Автор: Ouahab LahcГЁne, Yagubskii Eduard
Название: Organic Conductors, Superconductors and Magnets: From Synthesis to Molecular Electronics
ISBN: 1402019424 ISBN-13(EAN): 9781402019425
Издательство: Springer
Цена: 27066 р.
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Описание: The book covers different aspects of the chemistry and physics of molecular materials, including organic synthesis of specific organic donors and ligands, organic metals and superconductors, molecule-based magnets, multiproperty materials and organic-inorganic hybrids. The 17 chapters are written by some of the most authoritative authors in their field. The two last chapters are devoted to molecular electronics and devices, in particular the achievements and potential for applications. An excellent work for all students and researchers in organic conductors, superconductors and molecule based magnets.


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