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Visible Light Photocatalyzed Redox-Neutral Organic Reactions and Synthesis of Novel Metal-Organic Frameworks, Basudev Sahoo


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Автор: Basudev Sahoo
Название:  Visible Light Photocatalyzed Redox-Neutral Organic Reactions and Synthesis of Novel Metal-Organic Frameworks
ISBN: 9783319483498
Издательство: Springer
Классификация:



ISBN-10: 3319483498
Обложка/Формат: Hardback
Страницы: 258
Вес: 0.59 кг.
Дата издания: 2017
Серия: Springer theses
Язык: English
Издание: 1st ed. 2017
Иллюстрации: 37 illustrations, color; 76 illustrations, black and white; xxiii, 258 p. 113 illus., 37 illus. in color.
Размер: 234 x 156 x 18
Читательская аудитория: Professional & vocational
Ссылка на Издательство: Link
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Поставляется из: Германии
Описание: This unique thesis discusses the development of conceptually novel and synthetically valuable methods that use visible light photocatalysis. Each chapter addresses a different topic in the emerging field of photocatalysis, which has become an indispensable tool for organic synthesis. Photocatalysis employs environmentally harmless and abundant visible light in the presence of a photosensitizer, and as such offers an attractive alternative to harmful UV light in photo-mediated reactions. This book introduces the novel concept of merging gold catalysis with visible light photocatalysis in a dual catalytic fashion, which demonstrates their compatibility with each other for first time and has inspired the development of various reactions. Moreover, a novel trifluoromethylation method, which combines radical addition chemistry with a polar rearrangement to synthesize valuable fluorinated compounds, is presented, since compounds featuring fluorinated functionality are the subject of increasing attention in pharmaceutical, agrochemical and material research. It also develops an external photocatalyst-free photochemical method for the synthesis of valuable indolizine heterocycles, where the product mediates its own formation. Lastly, it describes the synthesis and characterization of two novel highly porous metal-organic frameworks (MOFs). The comprehensive text is rounded out with illustrations and color figures.

Дополнительное описание: Abstract.- Introduction to Photocatalysis.- Dual Gold and Visible Light Photoredox-Catalyzed Heteroarylations of Non-Activated Alkenes.- Visible Light Photoredox Catalyzed Trifluoromethylation-Ring Expansion via Semipinacol Rearrangement.- Transition Meta



Amino Acid and Peptide Synthesis

Автор: Jones, John
Название: Amino Acid and Peptide Synthesis
ISBN: 0199257388 ISBN-13(EAN): 9780199257386
Издательство: Oxford Academ
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Цена: 5226.00 р.
Наличие на складе: Поставка под заказ.

Описание: This is a thoroughly updated edition of one of the best selling titles in the Oxford Chemistry Primer series. John Jones provides an excellent, easy to read introduction to amino acid and peptide synthesis aimed at second and final year undergraduates.

Pericyclic reactions

Автор: Fleming, Ian (Reader in Organic Chemistry)
Название: Pericyclic reactions
ISBN: 0198503075 ISBN-13(EAN): 9780198503071
Издательство: Oxford Academ
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Цена: 2691.00 р.
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Описание: Pericyclic reaction - the third type of organic reaction mechanism along with ionic and radical reactions - include some of the most powerful synthetically useful reactions, like the Diels - Alder reaction, 1,3- dipolar cycloaddition the Alder ene reaction, Claisen rearrangements, the 2,3-Wittig rearrangement, diimide reduction, sulfoxide elimination and many others. These reactions are characterised by having cyclic transition structures, and also have highly predictable stereochemical features. Every organic chemist must be able to recognise the various types of pericyclic reaction and know something of their mechanisms and the factors that affect how well they work in organic synthesis. This book identifies the four main classes of pericyclic reaction, and discusses the main characteristics of the most important class, cycloadditions - providing a working knowledge, based on real examples, of their scope, patterns of reactivity, and stereochemistry. Then it explains the main features using ideas based in molecular orbital theory, but ( as in the companion book by A. J. Kirby on Stereoelectronic Effects ) without mathematics. It presents the Woodward - Hoffmann rules in the form of two all-encompassing rules, one for thermal reactions and its opposite for photochemical reactions. These rules are explained in detail and carefully illustrated, so that you will be able to predict the stereochemical outcome for any pericyclic reaction. The remaining chapters use this theoretical framework to show how the rules work with the other three classes of pericyclic reactions - electrocyclic reactions, sigmatropic rearrangements and group transfer reactions. By the end of the book, you will be able to recognise any pericyclic reaction and predict with confidence whether it is allowed, and with what stereochemistry, and you will have a working knowledge of the range of pericyclic reactions available to the synthetic organic chemist.

Mechanisms of Organic Reactions

Автор: Maskill, Howard (Senior Lecturer, University of Ne
Название: Mechanisms of Organic Reactions
ISBN: 0198558228 ISBN-13(EAN): 9780198558224
Издательство: Oxford Academ
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Цена: 5226.00 р.
Наличие на складе: Поставка под заказ.

Описание: The book begins with the modern concepts of organic chemical reactivity, then presents a concise up to date account of the mechanisms of major reactions of simple organic compounds. Each chapter leads the student from the experimental evidence to the mechanistic deductions, and ends with problems for students to work through, and a short bibliography.


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