Secheresse Francis Polyoxometalate Chemistry: Some Recent Trends 9789814458979

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Автор: Secheresse Francis
Название: Polyoxometalate Chemistry: Some Recent Trends
ISBN: 9789814458979
Издательство: World Scientific Publishing
Классификация:

Неорганическая химия

ISBN-10: 981445897X
Обложка/Формат: Hardback
Страницы: 360
Вес: 0.66 кг.
Дата издания: 21.08.2013
Серия: Physics
Язык: English
Размер: 231 x 147 x 20
Читательская аудитория: College/higher education
Ключевые слова: Inorganic chemistry, SCIENCE / Chemistry / Inorganic,SCIENCE / Nanoscience,TECHNOLOGY & ENGINEERING / Materials Science
Основная тема: Nanotechnology & Nanoscience / Nanomaterials And Nanostructures
Ссылка на Издательство: Link
Поставляется из: Англии
Описание: The book highlights recent prominent results in the domain of the synthesis of new polyoxometalates with a specific attention to polyoxothioanions, and provides some novelties and perspectives in selected domains such as magnetism, luminescence and nanochemistry, and macroions self-assembly in solutions. The case of one-pot syntheses often used and reported in POMs synthesis is studied in terms of more complex solution speciation processes related to highly dynamical situation connected to factors such as pH, ionic strength, reaction time, temperature, counterion nature, concentration of starting materials, presence of electron donors and redox potentials. The behavior of macroions (2nm-6nm size range) in solution is shown to be quite different from the simple ionic solution or colloidal systems (Debye-Huckel model). Their self-assembling into a single-layered, spherical, hollow vesicle structure, namely the blackberry structure, is clearly described. Examples of spin clusters with tunable interactions are given and single molecule magnets based on POMs are specifically tackled. Besides paramagnetic transition metal centres and lanthanoid ions encapsulated in archetypal lacunary polyoxoanions, magnetically functionalized Kleperates are described, their discovery tracing back nearly 15 years.

Polyoxometalate Chemistry: Some Recent Trends, Secheresse Francis