Описание: This book, aimed at academic and industrial scientists, presents the most advanced theory and methods of chemical kinetics. The theory is explained on the basis of the author's historical and logical view of traditional kinetics, beginning with van't Hoff and S. Arrhenius and progressing to the work of H. Eyring, E. Wigner and J. Horiuti. The theory has been applied to the understanding of Ziegler-Natta-Kaminsky catalysis, the results being supported by the author's own experimental studies. Organic chemists interested in finding new active catalysts will learn from this text how to understand the fundamental and practical kinetic method as relevant for catalyst research in industry and universities.
Автор: Mariam Al-Ali AlMa`adeed; Igor Krupa Название: Polyolefin Compounds and Materials ISBN: 3319259806 ISBN-13(EAN): 9783319259802 Издательство: Springer Рейтинг: Цена: 18284.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: Introduction.- Polyolefins - the history and economic impact.- Olefin Polymerization.- Processing Techniques for Polyolefins.- Polyolefin Blends.- Polyolefin Composites and Nano-Composites.- Polyolefin in the Packaging and Food Industry.- Polyolefin Adhesion Modifications.- Polyolefins in Textiles and Non-wovens.- Biomedical Applications of Polyolefins.- Polyolefins in Automotive Industry.- Polyolefins: From Thermal and Oxidative Degradation to Ignition and Burning.- Recycling of Polyolefin Materials.- Oxo-biodegradable Plastics: What They Are and To What They Serve - Present Status and Future Perspectives.
Автор: Oskar Nuyken Название: Neodymium Based Ziegler Catalysts - Fundamental Chemistry ISBN: 3642071120 ISBN-13(EAN): 9783642071126 Издательство: Springer Рейтинг: Цена: 48774.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: Even though Ziegler catalysts have been known for almost half a century, rare earth metals (Ln), particularly neodymium (Nd)-based Ziegler catalyst systems, only came into the focus of industrial and academic research well afterthelargescaleapplicationoftitanium, cobaltandnickelcatalystsystems. Asadirectconsequenceofthelaterecognitionofthetechnologicalpotentialof rareearthmetalZieglercatalysts, thesesystemshaveattractedmuchattention. Considerable progress has been made in this ?eld as a result of intensive workperformed during the last fewyears. Worthmentioning is thestructural identi?cation of a variety of Ln/Al heterobimetallic complexes and the role of alkyl aluminum cocatalysts in molar mass control. Furthermore, a deeper understanding ofthe polymerization mechanism, suchas theliving character of neodymium-catalyzed diene polymerization associated with the reversible transfer of living polymer chains between Nd and Al, was revealed quite - cently. In spite of the vast number of patents and publications mainly issued duringthelastdecade, acomprehensivereviewthatcoversthescienti?caswell as the patent literature has been missing until now. In this volume we try to review the available literature by two independent approaches to Nd and Ln-catalyzed diene polymerizations. In the ?rst part of thevolume, whichisentitled"Neodymium-Based Ziegler/NattaCatalystsand their Application in Diene Polymerization", a polymer chemist's view is given with strong emphasis on Nd-based catalyst systems. Also technological and industrialaspectsofNd-catalyzeddienepolymerizationsareaddressed.Inthe secondpartofthevolume, whichisentitled"Rare-EarthMetalsandAluminum Getting Close in Ziegler-type Organometallics", a more organometallic p- spective isgivenandLn-based catalystsystems areaddressed. Bythesynopsis of these different perspectives, the reader will comprehend the complexity of Ln-based Ziegler catalyst systems and their application to the polymerization of dienes. This volume also gives a description ofthe evolution in Nd-catalyzed po- merization of dienes from the early works to the current state of the art.
Автор: Walter Kaminsky Название: Polyolefins: 50 years after Ziegler and Natta II ISBN: 3642408044 ISBN-13(EAN): 9783642408045 Издательство: Springer Рейтинг: Цена: 43100.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist.
Автор: Ann-Christine Albertsson Название: Long-Term Properties of Polyolefins ISBN: 3662145669 ISBN-13(EAN): 9783662145661 Издательство: Springer Рейтинг: Цена: 32142.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Автор: F.B. Seymour; Tai Cheng Название: History of Polyolefins ISBN: 9401089167 ISBN-13(EAN): 9789401089166 Издательство: Springer Рейтинг: Цена: 26122.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Автор: Harald Pasch; Muhammad Imran Malik Название: Advanced Separation Techniques for Polyolefins ISBN: 3319086316 ISBN-13(EAN): 9783319086316 Издательство: Springer Рейтинг: Цена: 9794.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: Advanced Separation Techniques for Polyolefins
Описание: Includes: "Technology and Development of Self-Reinforced Polymer Composites"; "Recent Advances in High-Temperature Fractionation of Polyolefins"; "Antibacterial Peptidomimetics: Polymeric Synthetic Mimics of Antimicrobial Peptides"; "Collagen in Human Tissues: Structure, Function, and Biomedical Implications from a Tissue Engineering Perspective".
Название: Ziegler catalysts ISBN: 3642791387 ISBN-13(EAN): 9783642791383 Издательство: Springer Рейтинг: Цена: 14365.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: Forty years after Ziegler's discovery of the "Aufbaureaktion" and low-pressure ethene polymerization, transition metal catalyzed olefin and diolefin polymerization continues to represent one of the most active and exciting areas. Since the 1980s, outstanding scientific innovations and process improvements have revolutionized polyolefin technology and greatly simplified polymerization processes. Well-defined catalyst systems are now at hand and facilitate the understanding of basic reaction mechanisms and correlations between catalyst structures, polymer microstructures, and polymer properties. This book reviews some of the modern approaches in organometallic chemistry, Ziegler-Natta catalysis, polymerization processes, design of novel materials, and the modelling in catalyst and process development.
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