Energetics of Organic Free Radicals, Jos? A. Martinho Sim?es; Joel F. Liebman; A. Green

Автор: Jos? A. Martinho Sim?es; Joel F. Liebman; A. Green
Название: Energetics of Organic Free Radicals
ISBN: 9401065322 ISBN-13(EAN): 9789401065320
Издательство: Springer
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Описание: The current volume consists of eight chapters which interweave various aspects of the structure, energetics and reactivity of organic free radicals, all combining pedagogical insights with current research. The first is by Walling in which a personalized overview is given by one of the modern pioneers of the discipline. In the next two chapters, Tsang, and Traeger and Kompe, present key thermochemical and kinetic quantities from the complementary vantage points of the studies of neutral and cationic species. The fourth chapter by Francisco and Montgomery discusses the armamentarium of modern theory as applied to species with unpaired electrons, while the next chapter by Goodman presents the theory, methodology and results from photoacoustic calorimetry, a novel and powerful experimental technique. Martinho Simoes and Minas da Piedade interrelate organometallic and free radical chemistry, while Greenberg and Liebman consider resonance energy and rearrangements as applied to small molecules and enzyme cofactors alike. The volume ends with the chapter by Tanko and Suleman, which describes the surprising and diverse solvent effects which modulate free radical chem- istry. This volume will make it apparent to entry-level graduate students and senior researchers alike that much is known and much remains to be done in both the qualitative understanding and quantitative insights of the chemistry of organic free radicals. Jose Artur Martinho Simoes Arthur Greenberg Joel F. Liebman vii Editorial Advisory Board WESTON T. BORDEN ALAN P.

Автор: Jos? A. Martinho Sim?es
Название: Energetics of Organometallic Species
ISBN: 9401050880 ISBN-13(EAN): 9789401050883
Издательство: Springer
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Цена: 12157.00 р.
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Описание: Proceedings of the NATO Advanced Study Institute, Curia, Portugal, September 3-13, 1991

Автор: D. I. Davies; M. J. Parrott
Название: Free Radicals in Organic Synthesis
ISBN: 3642669247 ISBN-13(EAN): 9783642669248
Издательство: Springer
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Описание: Free Radical Chemistry has a comparatively long history. Before the accep- tance of the quadrivalence of carbon, various attempts were made to prepare trivalent carbon species like methyl and ethyl. Initial investigations involving reaction between alkyl iodides and zinc were thought to be successful \ but were subsequently branded as failures 2. In fact free methyl and ethyl were transient radicals involved in the reactions, but because of their short lifetimes the radicals were not detected, and only the hydrocarbons formed by dimeri- th sation of the radicals were isolated. At the beginning of the 20 century Gom- berg discovered the stable triarylmethyl radicals 3, and then in the 1920's Pa- neth 4 showed that free alkyl radicals could have a short lifetime in the gas phase. Free radicals as intermediates in reactions in solution were largely un- recognised until in 1937 Hey and Waters 5 interpreted a number of reactions, which did not fit into the then developing electronic theory of Organic Chem- istry6,7, by suggesting that they involved the intermediacy of free radicals. The other contemporary pioneer Kharasch 8 also proposed free radicals as interme- diates in certain reactions in solution, many involving organometallic species. However in the 1930 - 1950 period free radicals were not universally accepted as respectable reaction intermediates as evidenced by the initial rejection of the work of Koelsch 9 and the stand against free radicals made by Hodgson 10.

Автор: Hanns Fischer; Heinz Heimgartner
Название: Organic Free Radicals
ISBN: 3540501290 ISBN-13(EAN): 9783540501299
Издательство: Springer
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Автор: Halliwell, Barry; Gutteridge, John
Название: Free Radicals in Biology and Medicine
ISBN: 019856869X ISBN-13(EAN): 9780198568698
Издательство: Oxford Academ
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Цена: 11088.00 р.
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Описание: Provides coverage of isoprostanes and related compounds, mechanisms of oxidative damage to DNA and proteins (and the repair of such damage), the free radical theory of ageing and the roles played by reactive species in signal transduction, cell death, human reproduction, and other important biological events.

Автор: F. Minisci
Название: Free Radicals in Synthesis and Biology
ISBN: 9401068925 ISBN-13(EAN): 9789401068925
Издательство: Springer
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Описание: Proceedings of the NATO Advanced Research Workshop, Bardolino (VR), Italy, May 8-13, 1988

Автор: Markus Heinrich; Andreas Gans?uer
Название: Radicals in Synthesis III
ISBN: 3642436102 ISBN-13(EAN): 9783642436109
Издательство: Springer
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Цена: 45712.00 р.
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Описание: Radical Catalysis by Group 4 to Group 7 Elements, by Ullrich Jahn.- Radicals in Transition Metal Catalyzed Reactions? Transition Metal Catalyzed Radical Reactions?: A Fruitful Interplay Anyway Part 3: Catalysis by Group 10 and 11 Elements and Bimetallic Catalysis, by Ullrich Jahn.-

Автор: Andreas Gans?uer
Название: Radicals in Synthesis I
ISBN: 3642068413 ISBN-13(EAN): 9783642068416
Издательство: Springer
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Цена: 36570.00 р.
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Описание: This series presents critical reviews of the present position and future trends in modern chemical research. Scientists and practitioners in the mentioned fields and in industry will benefit from this series. Further information as well as the electronic version of the whole content is available at: springerlink.com

Автор: Andreas Gans?uer
Название: Radicals in Synthesis II
ISBN: 3642068405 ISBN-13(EAN): 9783642068409
Издательство: Springer
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Описание: This book presents critical reviews of the present position and future trends in modern chemical research. The information remains valid and useful after 5 or 10 years. More information, as well as the electronic version of the whole content, is available at: springerlink.com.