Описание: Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium and rhodium.
Описание: Antoine Simonneau`s thesis highlights the development of new cycloisomerization reactions through the activation of alkynes with gold complexes.
Автор: Shinji Murai Название: Activation of Unreactive Bonds and Organic Synthesis ISBN: 3642084362 ISBN-13(EAN): 9783642084362 Издательство: Springer Рейтинг: Цена: 43100.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: With contributions by numerous experts
Название: C-h bond activation and catalytic functionalization ii ISBN: 3319248022 ISBN-13(EAN): 9783319248028 Издательство: Springer Рейтинг: Цена: 32652.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry.
Автор: Pierre H. Dixneuf; Henri Doucet Название: C-H Bond Activation and Catalytic Functionalization I ISBN: 3319246283 ISBN-13(EAN): 9783319246284 Издательство: Springer Рейтинг: Цена: 36570.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry.
Автор: E.G. Derouane; Jerzy Haber; Francisco Lemos; Ferna Название: Catalytic Activation and Functionalisation of Light Alkanes ISBN: 0792349601 ISBN-13(EAN): 9780792349600 Издательство: Springer Рейтинг: Цена: 43184.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: Light alkanes tend to be resistant to many forms of activation. This book covers homogeneous, heterogeneous and biological catalysis and helps readers to gain an awareness of progress and ideas in research areas different from their own. It is intended for newcomers and senior researchers in the field of alkane activation.
Описание: Antoine Simonneau`s thesis highlights the development of new cycloisomerization reactions through the activation of alkynes with gold complexes.
Автор: Jin-Quan Yu; Zhangjie Shi Название: C-H Activation ISBN: 3642263593 ISBN-13(EAN): 9783642263590 Издательство: Springer Рейтинг: Цена: 49631.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: Synthesis in the Key of Catellani: Norbornene-Mediated ortho C-H Functionalization.- Mechanistic Considerations in the Development and Use of Azine, Diazine and Azole N-Oxides in Palladium-Catalyzed Direct Arylation.- Palladium and Copper Catalysis in Regioselective, Intermolecular Coupling of C-H and C-Hal Bonds.- Pd-Catalyzed C-H Bond Functionalization on the Indole and Pyrrole Nucleus.- Remote C-H Activation via Through-Space Palladium and Rhodium Migrations.- Palladium-Catalyzed Aryl-Aryl Bond Formation Through Double C-H Activation.- Palladium-Catalyzed Allylic C-H Bond Functionalization of Olefins.- Ruthenium-Catalyzed Direct Arylations Through C-H Bond Cleavages.- Rhodium-Catalyzed C-H Bond Arylation of Arenes.- Cross-Dehydrogenative Coupling Reactions of sp3-Hybridized C-H Bonds.- Functionalization of Carbon-Hydrogen Bonds Through Transition Metal Carbenoid Insertion.- Metal-Catalyzed Oxidations of C-H to C-N Bonds.
Описание: This thesis presents the latest developments in new catalytic C–C bond formation methods using easily accessible carboxylate salts through catalytic decarboxylation with good atom economy, and employing the sustainable element iron as the catalyst to directly activate C–H bonds with high step efficiency. In this regard, it explores a mechanistic understanding of the newly discovered decarboxylative couplings and the catalytic reactivity of the iron catalyst with the help of density functional theory calculation. The thesis is divided into two parts, the first of which focuses on the development of a series of previously unexplored, inexpensive carboxylate salts as useful building blocks for the formation of various C–C bonds to access valuable chemicals. In turn, the second part is devoted to several new C–C bond formation methodologies using the most ubiquitous transition metal, iron, as a catalyst, and using the ubiquitous C–H bond as the coupling partner.
Описание: Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium and rhodium.
Автор: L?szl? I. Sim?ndi Название: Catalytic Activation of Dioxygen by Metal Complexes ISBN: 9401052654 ISBN-13(EAN): 9789401052658 Издательство: Springer Рейтинг: Цена: 27950.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: The activation of dioxygen by metal ions has both synthetic potential and biological relevance. An introductonary chapter reviews the chemistry of transition metal dioxygen complexes, which are usually the active intermediates in the catalytic reactions discussed.
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