Hartmut Yersin; D. Donges; D.R. Gamelin; H.U. G?de Transition Metal and Rare Earth Compounds 9783642087578

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Автор: Hartmut Yersin; D. Donges; D.R. Gamelin; H.U. G?de
Название: Transition Metal and Rare Earth Compounds
ISBN: 9783642087578
Издательство: Springer
Классификация:

Неорганическая химия

Органическая химия

Физическая химия

Лазерные технологии и голография

ISBN-10: 3642087574
Обложка/Формат: Paperback
Страницы: 186
Вес: 0.29 кг.
Дата издания: 04.12.2010
Серия: Topics in Current Chemistry
Язык: English
Размер: 234 x 156 x 11
Основная тема: Chemistry
Подзаголовок: Excited States, Transitions, Interactions II
Ссылка на Издательство: Link
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Поставляется из: Германии
Описание: There exists a large literature on the spectroscopic properties of copper(II) com- 9 pounds. This is due to the simplicity of the d electron configuration, the wide variety of stereochemistries that copper(II) compounds can adopt, and the f- xional geometric behavior that they sometimes exhibit 1]. The electronic and geometric properties of a molecule are inexorably linked and this is especially true with six-coordinate copper(II) compounds which are subject to a Jahn-T- ler effect.However, the spectral-structural correlations that are sometimes d- wn must often be viewed with caution as the information contained in a typical solution UV-Vis absorption spectrum of a copper(II) compound is limited. Meaningful spectral-structural correlations can be obtained in a related series of compounds where detailed spectroscopic data is available. In the fol- 4- lowing sections two such series are examined; the six-coordinate CuF and 6 2+ Cu(H O) ions doped as impurities in single crystal hosts.Using low tempera- 2 6 ture polarized optical spectroscopy and electron paramagnetic resonance, a very detailed picture can be drawn about the geometry of these ions in both their ground and excited electronic states. We then compare the spectrosco- cally determined structural data with that obtained from X-ray diffraction or EXAFS measurements.

Transition Metal and Rare Earth Compounds, Hartmut Yersin; D. Donges; D.R. Gamelin; H.U. G?de