Автор: Cornell Название: A Primer on Experiments with Mixtures ISBN: 0470643382 ISBN-13(EAN): 9780470643389 Издательство: Wiley Рейтинг: Цена: 17416.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: The concise yet authoritative presentation of key techniques for basic mixtures experiments Inspired by the author`s bestselling advanced book on the topic, A Primer on Experiments with Mixtures provides an introductory presentation of the key principles behind experimenting with mixtures.
Автор: Suojiang Zhang; Qing Zhou; Xingmei Lu; Yuting Song Название: Physicochemical Properties of Ionic Liquid Mixtures ISBN: 9401775710 ISBN-13(EAN): 9789401775717 Издательство: Springer Рейтинг: Цена: 27950.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание:
Part I Ionic Liquids Database.- Ionic Liquids Database.- Introduction.- Properties of Multi-Systems Containing Ionic Liquids.- The Usage of Database.- Part II Properties of Multi-Systems Containing Ionic Liquids.- Systems Containing Imidazolium Ionic Liquids.- Systems Containing 1-Alkyl Imidazolium Ionic Liquids.- Systems Containing 1,3-Dialkyl Imidazolium Ionic Liquids.- Systems Containing Tri-Alkyl Imidazolium Ionic Liquids.- Systems Containing Pyrrolidinium Ionic Liquids.- Systems Containing Piperidinium Ionic Liquids.- Systems Containing Pyridinium Ionic Liquids.- Systems Containing Isoquinolinium Ionic Liquids.- Systems Containing Ammonium Ionic Liquids.- Systems Containing Phosphonium Ionic Liquids.
Описание: Abstract: A solution of groups technique was developed for use with fluctuation solution theory. The general expressions for calculation of pressure and chemical potential changes from some fixed reference states have been shown. A new corresponding states theory correlation for direct correlation function integrals was proposed and used with the group contribution technique for calculation of pressure changes during compression for several n-alkanes and methanol. This work gives a detailed analysis of the RISM theory of liquids. Shown are new results for perturbation theory and a generalized compressibility theorem for RISM fluids. The use of the RISM theory for calculation of thermodynamic properties of real fluids also is given. The use of hard sphere reference fluids for development of equations of state has been explored. A generalized hard sphere equation of state was developed. It was shown that the most accurate hard sphere equation of state is not the best reference system for construction of a liquid phase equation of state of the van der Waals form. Dissertation Discovery Company and University of Florida are dedicated to making scholarly works more discoverable and accessible throughout the world. This dissertation, "Thermodynamic Properties of Multicomponent Mixtures From the Solution of Groups Approach to Direct Correlation Function Solution Theory" by John Charles Telotte, was obtained from University of Florida and is being sold with permission from the author. A digital copy of this work may also be found in the university's institutional repository, IR@UF. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation.
Автор: Coleman, Michael M. , Painter, Paul C. , Graf, J Название: Specific Interactions and the Miscibility of Polymer Blends ISBN: 0367401517 ISBN-13(EAN): 9780367401511 Издательство: Taylor&Francis Рейтинг: Цена: 10104.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание:
This book with software provides powerful tools for the analysis, prediction and creation of new polymer blends, an area of significant commercial potential. The R&D approaches and methods described in the book have attracted the interest of polymer R&D leaders in industry, and have been put into use in several major chemical companies. The companion set of computer programs speeds and facilitates work in this area.
FROM THE AUTHORS' PREFACE: During the 1980's a steadily increasing number of compatible systems [polymer blends] have been reported. We believe that miscible mixtures will prove to be fairly common and the purpose of this book is to explore the circumstances in which single phase materials can be obtained. We will also describe a model for the phase behavior of these mixtures which we believe to have a predictive value, or be used as a practical guide to polymer miscibility. Our approach is based on the use of association models which have until recently been largely ignored in treating hydrogen bonding in polymer mixtures. They have most frequently been applied to mixtures of alcohols with simple hydrocarbons, where the equilibrium constants used to describe association have most frequently been determined by a fit to thermodynamic data (e.g., vapor pressures, heat of mixing). In our work we have sought to, first, adapt this approach to a description of the phase behavior of polymer mixtures; second, develop spectroscopic methods that provide an independent measurement of the equilibrium constants. Our purpose in this book is to explore and describe this approach and illustrate its broad utility. We address two overlapping yet different audiences. One would be primarily interested in the broad nature of this approach and the practical applications of a simple model. The second would be more interested in the derivations of the equations and some of the fundamental aspects of the spectroscopy of these systems. Accor
Описание: Abstract: A solution of groups technique was developed for use with fluctuation solution theory. The general expressions for calculation of pressure and chemical potential changes from some fixed reference states have been shown. A new corresponding states theory correlation for direct correlation function integrals was proposed and used with the group contribution technique for calculation of pressure changes during compression for several n-alkanes and methanol. This work gives a detailed analysis of the RISM theory of liquids. Shown are new results for perturbation theory and a generalized compressibility theorem for RISM fluids. The use of the RISM theory for calculation of thermodynamic properties of real fluids also is given. The use of hard sphere reference fluids for development of equations of state has been explored. A generalized hard sphere equation of state was developed. It was shown that the most accurate hard sphere equation of state is not the best reference system for construction of a liquid phase equation of state of the van der Waals form. Dissertation Discovery Company and University of Florida are dedicated to making scholarly works more discoverable and accessible throughout the world. This dissertation, "Thermodynamic Properties of Multicomponent Mixtures From the Solution of Groups Approach to Direct Correlation Function Solution Theory" by John Charles Telotte, was obtained from University of Florida and is being sold with permission from the author. A digital copy of this work may also be found in the university's institutional repository, IR@UF. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation.
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