Donoshita Design of Crystal Structures Using Hydrogen Bonds on Molecular-Layered Cocrystals and Proton

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Автор: Donoshita
Название: Design of Crystal Structures Using Hydrogen Bonds on Molecular-Layered Cocrystals and Proton–Electron Mixed Conductor
ISBN: 9789819970612
Издательство: Springer
Классификация:

Физика конденсированных сред (физика веществ в жидком и твёрдом состоянии)

ISBN-10: 981997061X
Обложка/Формат: Hardback
Страницы: 79
Вес: 0.00 кг.
Дата издания: 18.01.2024
Серия: Springer theses
Язык: English
Издание: 1st ed. 2024
Иллюстрации: 49 illustrations, color; 8 illustrations, black and white; xii, 79 p. 57 illus., 49 illus. in color.
Размер: 235 x 155
Основная тема: Chemistry
Ссылка на Издательство: Link
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Поставляется из: Германии
Описание: This thesis addresses the design of crystal structures using hydrogen bonds. In particular, it focuses on the design of functionalities and the control over the packing of molecular assemblies, based on molecular designs. Firstly, the synthesis and evaluation of a proton–electron mixed conducting charge transfer salt is reported. Focusing on the difference in the strength of hydrogen bonds and weaker intermolecular interactions, a system was rationally designed and constructed where electron-conducting molecular wires were encapsulated within a proton-conducting matrix. Next, the investigation of structural phase transitions in a cocrystal consisting of hydrogen-bonded two-dimensional molecular assemblies is reported. Drastic rearrangements of hydrogen-bonded molecular assemblies in the cocrystal led to single-crystal-to-single-crystal phase transitions, resulting in anisotropic changes in the crystal shape. Furthermore, chemical modification of a component molecule in the cocrystal is reported. The modification afforded control over the stacking patterns of the two-dimensional molecular assemblies, i.e., sheets, and the mechanism was discussed considering the intersheet intermolecular interactions and molecular motion. It is suggested that hydrogen bonds are beneficial to construct molecular assemblies in molecular crystals because of their strength and well-defined directionality, and the consideration of coexisting weaker intermolecular interactions can lead to the design of whole crystal structures and, hence, functionalities. This thesis benefits students and researchers working on solid-state chemistry by presenting various methods for characterizing and evaluating the properties of molecular solids.
Дополнительное описание: General Introduction.- Rational Construction of Molecular Electron-conducting Nanowires Encapsulated in Proton-conducting Matrix in a Charge Transfer Salt.- Drastic Rearrangement of Self-assembled Hydrogen-bonded Tapes in a Molecular Crystal.- Various Sta

Design of Crystal Structures Using Hydrogen Bonds on Molecular-Layered Cocrystals and Proton–Electron Mixed Conductor, Donoshita