Strategies for Palladium-Catalyzed Non-Directed and Directed C-H, Kapdi, Anant R.
Автор: R.J. Puddephatt Название: Nickel, Palladium and Platinum, ISBN: 0080423167 ISBN-13(EAN): 9780080423166 Издательство: Elsevier Science Рейтинг: Цена: 43890 р. Наличие на складе: Поставка под заказ.
Описание: Presents the advances in the organometallic chemistry of nickel, palladium and platinum. This volume covers the fundamental organometallic chemistry which underpins these applications. It includes applications in catalysis such as the catalytic copolymerization of ethylene with carbon monoxide, and describes developments in C-H bond activation.
Автор: Chatani Название: Directed Metallation ISBN: 3540758089 ISBN-13(EAN): 9783540758082 Издательство: Springer Рейтинг: Цена: 36845 р. Наличие на складе: Поставка под заказ.
Описание: Directed metalation is recognized as one of the most useful methodologies for the regio- and stereoselective generation of organometallic species. A wide variety of catalytic functionalization reactions of C-H bonds by the utilization of a chelation, have been developed. This book discusses these by some of the leading experts.
Автор: Tsuji Jiro Название: Palladium in Organic Synthesis ISBN: 3540239820 ISBN-13(EAN): 9783540239826 Издательство: Springer Рейтинг: Цена: 48574 р. Наличие на складе: Поставка под заказ.
Описание: Palladium is a remarkable metal. In particular, organopalladium chemistry has made remarkable progress over the last 30 years. That progress is still continuing, without any end in sight. This book presents a number of accounts and reviews on the novel Pd-catalyzed reactions discovered mainly in the last five years. The book covers Pd-catalyzed reactions that are new вЂ“ entirely different from the more standard ones. Topics such as new reactions involving Гџ-carbon elimination and formation of palladacycles as key reactions, cross-coupling of unactivated alkyl electrophiles with organometallic compounds, arylation via C-H bond cleavage, Pd/norbornene-catalyzed aromatic functionalizations, three-component cyclizations of allenes, use of N-heterocyclic carbenes as ligands, asymmetric reactions catalyzed by Pd(II) compounds such as Lewis acids, cycloadditions of arynes and alkynes, and nucleophilic attack by Pd species are surveyed in detail by researchers who have made important contributions to these fields. The book addresses graduate students majoring in organic synthesis and researchers in academic and industrial institutes.
Автор: van Leeuwen P.W., Claver Carmen Название: Rhodium Catalyzed Hydroformylation ISBN: 1402004214 ISBN-13(EAN): 9781402004216 Издательство: Springer Рейтинг: Цена: 11872 р. Наличие на складе: Поставка под заказ.
Описание: In the last decade there have been numerous advances in the area of rhodium-catalyzed hydroformylation, such as highly selective catalysts of industrial importance, new insights into mechanisms of the reaction, very selective asymmetric catalysts, in situ characterization and application to organic synthesis. The views on hydroformylation which still prevail in the current textbooks have become obsolete in several respects. Therefore, it was felt timely to collect these advances in a book. The book contains a series of chapters discussing several rhodium systems arranged according to ligand type, including asymmetric ligands, a chapter on applications in organic chemistry, a chapter on modern processes and separations, and a chapter on catalyst preparation and laboratory techniques. This book concentrates on highlights, rather than a concise review mentioning all articles in just one line. The book aims at an audience of advanced students, experts in the field, and scientists from related fields. The didactic approach also makes it useful as a guide for an advanced course.
Автор: Naoto Chatani; L. Ackermann; B. Breit; C.-H. Jun; Название: Directed Metallation ISBN: 3642094937 ISBN-13(EAN): 9783642094934 Издательство: Springer Рейтинг: Цена: 36845 р. Наличие на складе: Поставка под заказ.
Описание: This book provides the broad scientific readership with a comprehensive summary and critical overview of a topic in organometallic chemistry. In addition, new approaches to directed hydrometalation and directed carbometalation as a key step are also discussed.
Автор: Thomas J.J. M?ller Название: Metal Catalyzed Cascade Reactions ISBN: 3642069509 ISBN-13(EAN): 9783642069505 Издательство: Springer Рейтинг: Цена: 41465 р. Наличие на складе: Поставка под заказ.
Описание: With contributions by numerous experts
Автор: MГјller Thomas J.J. Название: Metal Catalyzed Cascade Reactions ISBN: 3540329587 ISBN-13(EAN): 9783540329589 Издательство: Springer Рейтинг: Цена: 41465 р. Наличие на складе: Поставка под заказ.
Описание: Transition metal-catalyzed cascade reactions are an elegant approach to complex molecular scaffolds. Besides their esthetics and increase in structural complexity, they have also become mechanistic challenges for the combination of organometallic elementary steps. As a consequence, cascade reactions have revolutionized synthetic strategies and conceptual thinking. The authors highlight cyclization via carbopalladation and acylpalladation and Heck-pericyclic sequences. They discuss p-allyl palladium-based cascade reactions, Michael-type additions as an entry to transition-metal-promoted cyclizative transformations, and sequential or consecutive palladium-catalyzed processes, and show Pauson-Khand cascades, metal-catalyzed cyclizations of acyclic precursors, as well as cascade and sequential ruthenium-catalyzed transformations. Therefore, the reader finds overview of an exciting and highly dynamic field of a new and innovative methodological concept.
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