Автор: Michael Dub Название: Organometallic Compounds ISBN: 3662232170 ISBN-13(EAN): 9783662232170 Издательство: Springer Рейтинг: Цена: 12157.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: ___ -"S, . . C"'O, . . . P""E This non-critical compilation of literature data on organic drivatives of arsenic, antimony, and bismuth, reported after 1936, was prepared to provide an easy reference to the methods of their synthesis and to their physical and chemical properties. Biological properties of the organic derivatives of these three elements were not considered. The presence volume is based upon Chemical Abstracts (CA), Volume 31 (1937) through Volume 53(1959), and upon "Current Chemical Papers," published by the Chemical Society (London), issues for January through June 1960. For references published prior to 1937 the reader is referred to "Die Chemie der metall-organischen Verbindugen/' by E. Krause and A. vor. Grosse, Verlag von Gebrlider Borntraeger, Berlin, 1937. It should be pointed out that only compounds containing at least one carbon- arsenic, carbon-antimony, and carbon-bismuth bond, respectively, are included in the survey. HIGHLIGHTS The discovery of the chemotherapeutic efficacy of monosodium- arsanilate, 3,3'-diamino-4,4' -dihydroxyarsenobenzene, and 3-amino-4,4'-dihydroxy-3'- (sulfinomethylamino)arsenobenzene sodium salt (Atoxyl, Salvarsan, and Neosalvarson, respectively) provided inpetus to extensive research of organoarsenicals, which slakened only after the discovery of antibiotics. After 1936, a great variety of substituted arenearsonic and diarylarsinic acids was prepared and reduced to various types of trivalent arsenic derivatives, Further modifications of the Bart method were made, and aryldiazonium fluoroborates, chlorozincates, and chloroferrates, which are more stable than aryldiazonium chlorides, were introduced as the arylat- ing agents in the preparation of aromatic derivatives of arsenic.
Автор: Richard M. Stephenson Название: Flash Points of Organic and Organometallic Compounds ISBN: 9401160694 ISBN-13(EAN): 9789401160698 Издательство: Springer Рейтинг: Цена: 6986.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Автор: Michael C. B?hm Название: One-Dimensional Organometallic Materials ISBN: 3540172165 ISBN-13(EAN): 9783540172161 Издательство: Springer Рейтинг: Цена: 18167.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: This lecture note gives an analysis of electronic structure effects for a new class of molecular solids, i. The lecture note is hopefully a small contribution to enhance the general understanding of certain electronic properties in organo- metallic polymers. Also this lecture note is not free of this almost universal trend.
Автор: Spessard Gary O., Miessler Gary L. Название: Organometallic Chemistry ISBN: 0199342679 ISBN-13(EAN): 9780199342679 Издательство: Oxford Academ Рейтинг: Цена: 19734.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: Designed with the needs of both undergraduate and graduate students in mind, Organometallic Chemistry, Third Edition, covers the fundamentals of organometallic chemistry by presenting seminal experiments, analyzing real data, and offering the most comprehensive problem sets available. The text opens with careful explanations of the structure and bonding of organometallic compounds, providing a uniquely accessible introduction to the subject for undergraduate students. Later chapters build on this foundation with in-depth coverage of more advanced topics such as organometallic reaction mechanisms, catalysis, carbene complexes, metathesis, applications of organometallic chemistry to organic synthesis, and bioorganometallic chemistry.
Автор: Michael Dub Название: Organometallic Compounds Literature Survey 1937–1958 ISBN: 3662427958 ISBN-13(EAN): 9783662427958 Издательство: Springer Рейтинг: Цена: 12157.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: Photosensitization and photocatalysis refer to processes by which permanent chemical transformations are induced on substrates (organic/inorganic) by radiation to which the substrates themselves are transparent. Such transformations can be highly specific, very efficient, and occur under mild conditions. Herein lies the power of photochemical methods for possible applications in the field of conversion and storage of solar energy. This book provides a recent survey of the progress in this important area in catalysis, with an emphasis on inorganic complexes and organometallic compounds as the key light aborbers. The book is organized in three parts: fundamentals, followed by applications. Discussions cover a wide variety of photosensitized or photocatalyzed reactions: decomposition of water, reduction of CO2 and CO; spectral sensitization in photoelectrochemical cells; transformations (oxidation, reduction, isomerization, hydrogenation, dehydrogenation, carbonylation, etc.) of organics such as alkanes, alkenes, alcohols, etc. In view of the variety of systems (sensitizers, substrates) and the topics covered, the volume is unique in the field of photochemistry and will appeal to academic and industrial researchers in various subdisciplines of chemistry, material science and catalysis.
Автор: M. L. Green Название: Organometallic Compounds ISBN: 9401168954 ISBN-13(EAN): 9789401168953 Издательство: Springer Рейтинг: Цена: 6986.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: Contents Preface to the Third Edition, Volume Two Page v INTRODUCTION TO VOLUME TWO I Oassification I The IS-electron rule 2 (i) The basis of the I8-electron rule p. The preparation of olefin-transition metal complexes 7 (a) Displacement of solvent ligands p. Particular complexes of metals with 2-electron ligands 25 (a) Copper, silver and gold p.
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