Описание: Antoine Simonneau`s thesis highlights the development of new cycloisomerization reactions through the activation of alkynes with gold complexes.
Описание: Antoine Simonneau`s thesis highlights the development of new cycloisomerization reactions through the activation of alkynes with gold complexes.
Описание: This volume shows readers how theoretical calculations are used to determine, elucidate and propose mechanisms for Pd-catalyzed C-C cross-coupling reactions.
Описание: The series Topics in Heterocyclic Chemistry presents critical reviews on present and future trends in the research of heterocyclic compounds. Overall the scope is to cover topics dealing with all areas within heterocyclic chemistry, both experimental and theoretical, of interest to the general heterocyclic chemistry community. The series consists of topic related volumes edited by renowned editors with contributions of experts in the field.
Описание: This book offers reviews on synthesis of heterocycles via Metal-Catalyzed Alkene Carboamination, or Carboalkoxylation Reactions; Metal-Catalyzed Alkene Diamination, Aminoalkoxylation, or Dialkoxylation Reactions; Metal-Catalyzed Hydroamination and others.
Описание: This book offers reviews on synthesis of heterocycles via Metal-Catalyzed Alkene Carboamination, or Carboalkoxylation Reactions; Metal-Catalyzed Alkene Diamination, Aminoalkoxylation, or Dialkoxylation Reactions; Metal-Catalyzed Hydroamination and others.
Описание: This book presents a detailed study of the inter- and intramolecular reactions of carbonyl compounds with 1.6-enynes using gold (I) complexes. The lundurine products developed in this work show significant in vitro cytoxicity toward B16 melanoma cells.
Описание: This thesis presents the latest developments in new catalytic C–C bond formation methods using easily accessible carboxylate salts through catalytic decarboxylation with good atom economy, and employing the sustainable element iron as the catalyst to directly activate C–H bonds with high step efficiency. In this regard, it explores a mechanistic understanding of the newly discovered decarboxylative couplings and the catalytic reactivity of the iron catalyst with the help of density functional theory calculation. The thesis is divided into two parts, the first of which focuses on the development of a series of previously unexplored, inexpensive carboxylate salts as useful building blocks for the formation of various C–C bonds to access valuable chemicals. In turn, the second part is devoted to several new C–C bond formation methodologies using the most ubiquitous transition metal, iron, as a catalyst, and using the ubiquitous C–H bond as the coupling partner.
Описание: Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium and rhodium.
Описание: Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium and rhodium.
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