Описание: Antoine Simonneau`s thesis highlights the development of new cycloisomerization reactions through the activation of alkynes with gold complexes.
Описание: This volume shows readers how theoretical calculations are used to determine, elucidate and propose mechanisms for Pd-catalyzed C-C cross-coupling reactions.
Описание: A monograph that covers the activation and various transformations of saturated hydrocarbons (alkanes) - reactions accompanied by the C-H and C-C bond cleavage. It covers the reactions of saturated hydrocarbons, and considers the activation of C-H bonds in arenes and olefins and acetylenes.
Описание: Among hydrocarbons, saturated hydrocarbons, alkanes (methane, ethane, propane, hexane etc. Saturated hydrocarbons may be called the "noble gases of organic chemistry" and, if so, the first representative of their family - methane - may be compared with extremely inert helium.
Описание: This thesis presents the latest developments in new catalytic C-C bond formation methods using easily accessible carboxylate salts through catalytic decarboxylation with good atom economy, and employing the sustainable element iron as the catalyst to directly activate C-H bonds with high step efficiency.
Описание: Antoine Simonneau`s thesis highlights the development of new cycloisomerization reactions through the activation of alkynes with gold complexes.
Описание: This thesis presents the latest developments in new catalytic C–C bond formation methods using easily accessible carboxylate salts through catalytic decarboxylation with good atom economy, and employing the sustainable element iron as the catalyst to directly activate C–H bonds with high step efficiency. In this regard, it explores a mechanistic understanding of the newly discovered decarboxylative couplings and the catalytic reactivity of the iron catalyst with the help of density functional theory calculation. The thesis is divided into two parts, the first of which focuses on the development of a series of previously unexplored, inexpensive carboxylate salts as useful building blocks for the formation of various C–C bonds to access valuable chemicals. In turn, the second part is devoted to several new C–C bond formation methodologies using the most ubiquitous transition metal, iron, as a catalyst, and using the ubiquitous C–H bond as the coupling partner.
Описание: Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium and rhodium.
Описание: Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium and rhodium.
Автор: Matthias Beller; Xiao-Feng Wu Название: Transition Metal Catalyzed Carbonylation Reactions ISBN: 3642429173 ISBN-13(EAN): 9783642429170 Издательство: Springer Рейтинг: Цена: 18284.00 р. Наличие на складе: Есть у поставщика Поставка под заказ.
Описание: This book provides students and researchers in organic synthesis with a detailed discussion of carbonylation from the basics through to applications. It discusses the past, present and future of carbonylation reactions.
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